trans-Carbonylchloridobis[tris(4-chlorophenyl)phosphane]rhodium(I) acetone monosolvate
نویسندگان
چکیده
منابع مشابه
trans-Carbonylchloridobis[dicyclohexyl(4-isopropylphenyl)phosphane]rhodium(I) acetone monosolvate
The title rhodium Vaska-type complex, trans-[RhCl{P(C(6)H(11))(2)(C(6)H(4)-4-C(3)H(7))(2)}(2)(CO)], crystallizes with an accompanying acetone solvent mol-ecule. The metal atom shows a distorted square-planar coordination environment with selected important geometrical parameters of Rh-P = 2.3237 (6) and 2.3253 (6) Å, Rh-Cl = 2.3724 (6) Å, Rh-C = 1.802 (2) Å, P-Rh-P = 173.42 (2)° and Cl-Rh-C = 1...
متن کاملtrans-Carbonylchloridobis[tris(4-chlorophenyl)phosphane]rhodium(I) acetone monosolvate
The title compound, trans-[RhCl(C(18)H(12)Cl(3)P)(2)(CO)]·C(3)H(6)O, contains an Rh(I) atom in a distorted square-planar coordination with a P-Rh-P angle of 175.27 (2)° and Rh-P bond lengths of 2.3127 (4) and 2.3219 (4) Å. The rhodium complexes link each other through weak inter-molecular contacts between the acetone methyl groups and the carbonyl O atom. Inter-actions between the acetone solve...
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The title acetone solvate, C(42)H(28)O(2)·C(3)H(6)O [systematic name: 1,3,10,12-tetra-phenyl-19,20-dioxapenta-cyclo-[10.6.2.0(2,11).0(4,9).0(13,18)]icosa-2(11),3,5,7,9,13,15,17-octa-ene acetone monosolvate], is a photooxygenation product of rubrene (systematic name: 5,6,11,12-tetra-phenyl-tetra-cene). The mol-ecule bends at the bridgehead atoms, which are linked by the O-O transannular bond, wi...
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In the title compound, C(13)H(12)N(2)S·C(3)H(6)O, the phenyl rings of the thio-urea mol-ecule are in syn and anti positions in relation to the C=S bond. Two mol-ecules are connected by N-H⋯S=C hydrogen bonds into a centrosymmetric dimer. An additional N-H⋯O=C hydrogen bond to the acetone solvent mol-ecule and some weak C-H⋯π inter-actions reinforce the crystal structure.
متن کاملtrans-Dichloridobis[dicyclohexyl(4-isopropylphenyl)phosphane-κP]platinum(II) acetone monosolvate
The title compound, [PtCl(2)(C(21)H(33)P)(2)]·C(3)H(6)O, crystallizes with an accompanying acetone solvent mol-ecule. The metal atom shows a distorted square-planar coordination environment, with a P-Pt-P angle of 172.41 (3)° as the most prominent feature. Both isopropyl fragments were treated as disordered over two conformations with occupancy ratios of 0.55 (2):0.45 (2) and 0.58 (2):0.42 (2)....
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2010
ISSN: 1600-5368
DOI: 10.1107/s1600536810039814